采用泡沫铜电极的热再生氨电池性能数值模拟

以采用泡沫铜电极的热再生氨电池（thermally regenerative ammonia-based battery，TRAB）为研究对象，建立了多孔介质内物质传输与电化学反应耦合的稳态模型，计算获得了电池性能及多孔电极内物质传输特性，并研究了电解质浓度和电极孔隙率对电池性能的影响。研究结果表明，从主流区界面到多孔电极内部，阳极氨和阴极铜离子浓度逐渐降低，存在一定的浓度梯度，而且随着反应电流的增大，浓度梯度明显增大。在一定的范围内分别增大阳极氨浓度和阴极铜离子浓度，从主流区向多孔电极内物质传输增强，电池性能均能不断提升；随着硫酸铵浓度的增大，电解质电导率增大，电池性能逐渐提升，但增幅逐渐减小。此外，多孔电极孔隙率也会影响电池性能，本研究中TRAB在电极孔隙率为0.6时获得最高的最大功率(15.3 mW)。     

城镇化进程中农村集体资产管理问题探究

农村集体资产管理关系着农村经济的发展,对于社会的稳定和谐也有着重要影响,乡镇政府应加强对集体资产的重视,平衡乡镇改革与资产管理之间的关系,分析农村集体资产管理中存在的一些问题,结合自身的特点,采取有效的措施来促进其发展,加快城镇化农村集体资产管理显得尤为重要。     

User idea implementation in open innovation communities: Evidence from a new product development crowdsourcing community

In collaborative crowdsourcing communities for open innovation, users generate and submit ideas as idea co‐creators. Firms then select and implement valuable ideas for new product development. Despite the popularity and success of these open innovation communities, relatively little is known about the factors that determine the implementation of the user‐generated ideas. Based on research on individual creativity, we propose a conceptual model integrating users' previous experience, idea presentation characteristics and feedback valence to explain the likelihood of idea implementation. We validate our research model with a panel data analysis of 43 550 ideas submitted by 16 360 users in the MIUI new product development community hosted by Xiaomi, a large electronics manufacturing company in China. We find an inverted U‐shaped relationship between users' past successful experience and idea implementation. Furthermore, the length of ideas is positively associated with the likelihood of idea implementation. There is also an inverted U‐shaped relationship between supporting evidence and idea implementation. Finally, we demonstrate the negative effect of positive feedback and the positive effect of negative feedback on idea implementation. These findings offer rich insights to understand the phenomenon of open innovation better. Theoretical and practical implications are discussed.     

因子分析在冀东峪耳崖金矿地球化学找矿中的应用

峪耳崖金矿位于华北板块北缘，矿区基底地层为太古界迁西群麻粒岩相和角闪岩相，矿体受NNE—NE向断裂构造控制，赋矿围岩为花岗岩。在矿床地质特征基础上，利用矿区土壤地球化学数据，采取传统统计法和累计频率法圈定了金矿12个元素的异常范围；运用因子分析方法划分出了Sb Hg Pb As元素组合、Au Ag Bi元素组合、Zn Cu Sn元素组合和W Mo元素组合；再对因子得分进行趋势面分析，较为有效地突出了深层次的找矿信息，更准确地圈出成矿靶区。结合研究区地质特征认为Au Ag Bi元素组合和Sb Hg Pb As元素组合为研究区最佳地球化学标志元素组合，下一步地质工作重点应放在矿区中矿带矿体深部及其南部异常高值区，同时布置少量工程在北矿带，以追索与唐杖子金矿之间的联系。     

高速列车转向架构架损伤、等效应力及寿命分布特性研究

为分析高速列车转向架构架损伤、等效应力及寿命分布特性，对构架疲劳关键测点进行动应力线路实测并对测点实测时域数据波形进行解析；基于实测应力时间历程及雨流计数法编制二维应力谱，利用Goodman等寿命方程将二维应力谱等效转换为一维应力谱；阐述线性累积损伤及非线性累积损伤模型的建立方法并对实测数据的线性累积损伤及非线性累积损伤进行了计算及对比分析；分别基于线性累积损伤理论及非线性累积损伤理论推导出各理论下的等效应力，基于实测数据对两种等效应力进行了计算及对比分析；通过结合非线性累积损伤及线性累积损伤理论计算的等效应力及不同可靠度下的材料S-N曲线计算并对比分析构架结构的疲劳寿命。研究结果表明，与非线性疲劳分析理论相比，线性疲劳分析理论对高速列车转向架构架的疲劳特性评估偏于保守。     

Analysis of Fouling in Six-Start Spirally Corrugated Tubes

Abstract

Fouling on heat exchanger surfaces can weaken the heat-transfer capability, increase the energy consumption, and even cause the failure of the whole system. In coaxial heat exchangers, spirally corrugated tubes perform better than smooth ones concerning heat transfer and antifouling. In this article, a parametric study on the antifouling performance of a six-start spirally corrugated tube is carried out with a solid–liquid two-phase model. First, comparisons between a smooth tube and a specific sample six-start spirally corrugated tube on the solid particle volume fraction distributions are carried out. Then, the effects of solid particle diameter, the main geometric parameters, including pitch and the corrugation depth, are investigated. Analyzing the solid particle volume fraction with different geometries, solid particle diameters and Reynolds number, the roles played by the centrifugal force, drag force, and gravity of solid particles on fouling performance in six-start spirally corrugated tubes are obtained. In addition, the corrugation depth affects the volume fraction range more while the pitch affects more on the steady range of particle volume fraction. This work is of significance for further design of spirally corrugated tubes and analysis of fouling problems in heat exchangers.     

A novel flow field with controllable pressure gradient to enhance mass transport and water removal of PEM fuel cells

An easily machined novel flow field with controllable pressure gradient across adjacent channels was designed and a two dimensional, across-the-channel, two-phase model was developed to study the gas transport and water removal of the novel configuration. The effect of channel-rib width ratio, GDL thickness and pressure gradient on the profiles of oxygen concentration and water saturation within the GDL were investigated. Special attention was paid to the mechanisms of the promoted mass transport and water removal rates under a pressure gradient. The model was validated by experiments with various channel-rib ratios and GDL thicknesses at different operating pressure. The results revealed that, oxygen concentration was increased, and the water saturation was reduced under the rib with a pressure gradient generated across the adjacent channels. The optimal pressure gradient is between 0.1 to 0.2 atm for the studied channel geometry and configuration. The mechanisms of the improved cell performance were elucidated.     

木质素化学降解及其在聚合物材料中应用的研究进展

木质素是自然界储量丰富的可再生天然酚类高分子，可替代传统化石资源应用于聚合物材料合成。木质素分子结构中的大分子刚性骨架可赋予材料独特的力学性能和热稳定性。但木质素化学组成和分子结构复杂、反应活性低，限制了在聚合物材料领域的应用。化学降解是一种高效、高选择性且应用广泛的降解方法，经化学降解处理得到的木质素低聚物具有活性官能团多、反应活性高、溶解性好等优点，有利于拓展木质素在聚合物材料领域的高附加值应用。重点综述了近年来国内外有关木质素化学降解及其降解产物应用于聚合物材料的研究进展。     

长管拖车缠绕气瓶纤维层冲击损伤的数字射线检测

采用缠绕气瓶替代钢制无缝气瓶是长管拖车轻量化的重要手段之一,但对于缠绕气瓶缠绕层因冲击造成的内部损伤,目前仍缺少成熟有效的检测手段。采用数字射线检测方法,针对玻璃纤维缠绕层冲击损伤造成的分层和危害较大的纤维断裂进行了试验研究。试验表明,采用数字射线检测能够有效检测最小深度为0.5 mm模拟纤维环向断裂刻槽和0.25 mm的模拟纤维轴向断裂刻槽;此外,还通过试验验证增加补偿块的方式,能极大地改善缠绕层分层部位的一次切向透照成像质量,进而提高检测效率。     

山东栖霞—大柳行地区金矿找矿靶区地质评价及优选

栖霞—大柳行地区位于胶东中部栖霞—蓬莱金矿成矿带内，是胶东重要的金成矿区，成矿条件优越。为了对圈定靶区进行优选分类，通过对该区地质背景、找矿靶区评价、找矿靶区优选方面展开综合研究，并结合勘查工作程度和矿业权设置情况，划分出3类预测区，选定了5个靶区为今后优先部署勘查工作的方向。